This article “The Future”, Lockett (2022) introduces a new discovery
of lithium-sulphur batteries and how it will shape the future. Currently the
battery tech of choice has always been lithium-ion batteries, however they have
some downsides to using it.
The materials that are needed to build lithium-ion batteries
are lithium, graphite, cobalt and manganese. However raw material like cobalt is
environmentally damaging as they leach out toxic chemical when mining it. There
is also the life cycle problem where the lithium-ion battery will lose its
power storage capacity if it is repeatedly being charge them, and the battery
would have to be thrown away and contributed to electronic waste which is
becoming a problem for the world to deal with.
The discovery of lithium-sulphur has shown the potential to
replace the current battery choice as it is cheap and environmentally friendly compared
to lithium-ion. Furthermore, it is more energy dense and lightweight. However, the
drawback of lithium-sulphur is that they suffer from short lifespan.
Mining for materials use to make lithium-sulphur is cheap and
environmentally friendly is since Earth has abundant resources of lithium and
sulphur therefore that we can minimise the mining’s ecological impact as well
as ensure a stronger supply chain (Lockett, 2022). Sulphur is also a cheap raw
material as a by-product of the oil industry, and their costs per unit of power
can offer substantial savings (Merrifield, 2020) in terms of their theoretical
value compared to cobalt, one of the common elements in lithium-ion battery.
Another benefits to using lithium-sulphur battery is their
high energy density due to the composition of sulphur. The specific energy
density of lithium-ion is between 260 – 270 wh/kg (Dragonfly Energy, 2022),
while the theoretical value of lithium sulphur is 10 times that of lithium-ion,
estimated 2500 wh/kg. The higher the energy density, the longer the battery can
emit a charge in relation to its size, hence it is able to store a higher
amount of energy which allows the appliance to last for a longer period.
Despite the benefits of lithium-sulphur, the short lifespan of
sulphur is hindering it from becoming available to mass produce. The short life
cycle is due to its chemistry as charging the battery causes a build-up of
chemical deposits called polysulfides that will degrade the cell hence reduces
the amount of time the battery can be recharge repeatedly. However, scientists
have been trying to figure out ways to experiment on this chemical reaction in
order to reduce the build up of chemical deposits. According to William (2022),
the scientist at Drexel University found a chemical reaction of sulphur that
stops this cell degradation called monoclinic gamma-phase sulphur, which means
that the battery can charge for at least 4000 charge cycle without a drop in
capacity.
The scientists are still trying to decipher the phenomenon
behind this phase of sulphur that is created or how to ensure it stays that
way. So further research is needed in order to develop a reliable battery that
can be used in billions of computers, electric cars, and the like.
In conclusion, I believe that the use of lithium-sulphur
batteries could change human lives as it allows a huge range of activities to
go electric, allowing the emission of carbon dioxide to be much lesser there are
more benefits to using lithium-sulphur battery compared to lithium-ion battery,
in terms of its eco-friendliness, high energy capacity while being cost
efficient.
Park, J. W., Jo, S. C., Kim, M. J., Choi, I. H., Kim, B. G.,
Lee, Y. J., Choi, H. Y., Kang, S., Kim, TY., Baeg, K. J.,(2021, April 2)
Flexible high-energy-density lithium-sulphur batteries using
nanocarbon-embedded fibrous sulphur cathodes and membrane separators https://www.nature.com/articles/s41427-021-00295-y
Marrifield, R (2020, June 5) Cheaper, lighter and more
energy-dense: The promise of lithium-sulphur batteries https://ec.europa.eu/research-and-innovation/en/horizon-magazine/cheaper-lighter-and-more-energy-dense-promise-lithium-sulphur-batteries
Lockett, W (2022, April 17). The Future https://bigthink.com/the-future/lithium-sulfurbatteries/?utm_medium=Social&utm_source=Facebook&fs=e&s=cl&fbclid=IwAR1JQVrPK4Nt6YauDpwVZrmkeHE1jR0zfHdUdqe1wC5xr4XEabacCNVJLE#Echobox=1658939001-1
Dragonfly Energy (2022, December 14) https://dragonflyenergy.com/why-does-energy-density-matter-in-batteries/#:~:text=In%20fact%2C%20lithium-ion%20batteries,50-100%20wh%2Fkg.
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